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91.
The effect of end groups (2NH2) of poly(ethylene glycol) (PEG) on the miscibility and crystallization behaviors of binary crystalline blends of PEG/poly(L ‐lactic acid) (PLLA) were investigated. The results of conductivity meter and dielectric analyzer (DEA) implied the existence of ions, which could be explained by the amine groups of PEG gaining the protons from the carboxylic acid groups of PLLA. The miscibility of PEG(2NH2)/PLLA blends was the best because of the ionic interaction as compared with PEG(2OH, 1OH‐1CH3, and 2CH3)/PLLA blends. Since the ionic interaction formed only at the chain ends of PEG(2NH2) and PLLA, unlike hydrogen bonds forming at various sites along the chains in the other PEG/PLLA blend systems, the folding of PLLA blended with PEG(2NH2) was affected in a different manner. Thus the fold surface free energy played an important role on the crystallization rate of PLLA for the PEG(2NH2)/PLLA blend system. PLLA had the least fold surface free energy and the fast crystallization rate in the PEG(2NH2)/PLLA blend system, among all the PEG/PLLA systems studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
92.
宝钢曲轴用非调质钢的生产与展望   总被引:4,自引:0,他引:4  
在实验室研究的基础上,开发了屈服强度为520MPa级的曲轴用微合金化非调质钢48MnV。工业生产了6000余吨φ151mm大规格圆钢,其各项性能满足了用户要求。指出了宝钢曲轴用非调质钢开发和努力的方向。  相似文献   
93.
Heat convection in ballast mass in railway embankments is a problem of heat convection in porous media. In order to calculate the temperature distribution of the Qing-Tibet railway embankment from the governing equations used to study forced convection for incompressible fluids porous media, detailed finite-element formulas for heat convection in porous media are derived using Galerkin’s method. The temperature distributions on central lines of the traditional railway embankment, the ripped-rock embankment, and the ripped-rock revetment embankment that were constructed on July 15, 2002 have been analyzed and compared on July 15, October 15 in the 24th year after construction, and January 15 in the 25th year after construction under the climatic and geological conditions on the Qing-Tibet Railway. The calculated results indicate that the traditional railway embankment will raise the permafrost temperature under the embankment base and make the permafrost embankment thermally unstable. The ripped-rock embankment and the ripped-rock revetment embankment will reduce the permafrost temperature under the embankment base in cold regions, therefore maintaining the thermal stability of permafrost. However, the ripped-rock embankment needs more rock mass while the ripped-rock revetment embankment need less rock mass, and its construction cost is lower than that of the former. Therefore, it is highly recommended that the ripped-rock revetment embankment be used for the Qing-Tibet railway embankment structure in high temperature permafrost regions so that the permafrost embankment can be protected as much as possible.  相似文献   
94.
The aim of this study is to investigate means of efficiently assessing the effects of distributed structural modification on the dynamic properties of a complex structure. The dynamic properties of the modified structure can be determined by experimental testing or numerical simulation, both of which are complex, expensive and time-consuming. Assuming that the original dynamic characteristics are already established and that the modification is a relatively simple attachment, the modified dynamic properties may be determined numerically without solving the equations of motion of the full-modified structure. The frequency response functions (FRFs) of the modified structure can be computed by coupling the original FRFs and a delta dynamic stiffness matrix for the modification introduced. The validity of this approach is investigated by applying it to a cantilever beam to which a smaller beam is attached as modification. The original FRFs were obtained experimentally as well as numerically. The delta dynamic stiffness matrix was determined numerically by modeling the attachment and part of the original structure including the attachment points. The FRFs of the modified beam were then computed. Good agreement is obtained by comparing the results to the FRFs of the modified beam determined experimentally as well as by numerical modeling of the complete modified structure.  相似文献   
95.
Hong Kong is known as a migrant city because its population was sourced from mainland China, and because there has always been outflows of people to overseas countries, especially from the mid-1980s to mid-1990s. Emigration to mainland China has become a significant recent trend. This article discusses this phenomenon in the theoretical contexts of migration and trans-border residential development. It contends that the trend will intensify more quickly than other cross-border movements because the two systems are separated by a political border within one country, and because there are common cultural ties and rapid economic integration.  相似文献   
96.
本文通过建立几何模型 ,讨论了高速转镜相机光束倾斜入口的成象原理。证实了倾斜光束入口在转镜旋转时成象点的扫描轨迹是在以入射点为顶点 ,以成象点和入射点的连线为母线扫出的正圆锥底面的平面内 ,从而把空间光学的复杂设计问题简化成平面上的设计。此原理已用于 PDF- 2 0 0型平面转镜等待式分幅相机的设计  相似文献   
97.
The intratracheal instillation of xanthine-xanthine oxidase caused a marked decrease in dynamic respiratory compliance, indicating airway constriction. The constriction was significantly attenuated by fullerenol-1, but not by other agents or receptor antagonists.  相似文献   
98.
The fracture toughness J Ic (ρ) and fractal dimension D f of fractured surfaces of CuNiAl single crystal have been measured at temperatures in the range 20 °C to 120 °C, in which thermoelastic martensitic transformation takes place. The parent phase has higher fracture toughness than the martensite phase due to stress-induced transformation. The relationship between J Ic (ρ) and D f has been studied. It was found that log J Ic (ρ) is linearly related to D f if the failure involves a single mechanism. The slope of the plot may either be positive or negative for brittle or ductile failure, respectively. The difference in the J Ic (ρ)-D f correlation can be understood in terms of the micromechanism of fracture.  相似文献   
99.
黄仕香  赖爱平 《特种结构》2007,24(3):61-62,92
本文给出了用加强板加大管道截面系数来增加架空输水管道跨越距离的设计方法及其计算过程,并用实例说明了用此种方法加强大跨度管道的有效性和合理性。  相似文献   
100.
An approach to aid decision making for urban water management is presented that is based on the concept of trade-off sacrifice level in pairwise comparisons between criteria, modelled using fuzzy logic. This approach is illustrated by a case study - selection of alternative water supplies for a Sydney household. Four key decision making criteria covering health, economic, environment and technical aspects are selected: annual probability of infection, life cycle energy use, life cycle cost and reliability. The decision making problem is to select between cases with different volume and application of recycled greywater and rainwater in light of the four criteria. Decision maker's preference is expressed by five levels of trade-off sacrifice between pairs of criteria. The decision makers can assign their preferences for sacrifice level by linguistic assessment and the output trade-off weight (TOW). Measures of decision makers' perceived trade-off level are modelled by a rule-based fuzzy logic control system. The final analysis shows the performance for each sacrifice class for each case, to aid overall decision making with stakeholders.  相似文献   
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